In this episode, Claire and Jamie face challenges as they try to navigate their relationship amidst the dangers of the Jacobite uprising. Meanwhile, Claire's husband, Frank, becomes increasingly suspicious of her activities in the past.
The episode you're referring to is likely the ninth episode of the first season of Outlander, which is titled "To Ransom a Man's Soul and Bind His Wounds". This episode originally aired on November 8, 2014. outlander s01e09 1080p web-dl